Towards Substrate–Reagent Interaction of Lochmann–Schlosser Bases in THF: Bridging THF Hides Potential Reaction Site of a Chiral Superbase

The metalation of N,N‐dimethylaminomethylferrocene in THF by the superbasic mixture of ( n )BuLi/KO( t )Bu proceeds readily at low temperatures to afford a bimetallic Li(2)K(2) aggregate containing ferrocenyl anions and tert‐butoxide. Starting from an enantiomerically enriched ortho‐lithiated aminom...

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Detalles Bibliográficos
Autores principales: Brieger, Lukas, Schrimpf, Tobias, Scheel, Rebecca, Unkelbach, Christian, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092790/
https://www.ncbi.nlm.nih.gov/pubmed/36098179
http://dx.doi.org/10.1002/chem.202202660

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092790/
https://www.ncbi.nlm.nih.gov/pubmed/36098179
http://dx.doi.org/10.1002/chem.202202660

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