Room‐Temperature‐Observable Interconversion Between Si(IV) and Si(II) via Reversible Intramolecular Insertion Into an Aromatic C−C Bond

An easily isolable silacycloheptatriene (silepin) 1  b was synthesized from the reaction of a N‐heterocyclic imino (IPrN) substituted tribromosilane IPrNSiBr(3) with the sterically congested bis(trimethylsilyl)triisopropylsilyl silanide KSi(TMS)(2)Si(( i )Pr)(3) (BTTPS). In solution, the Si(IV) sile...

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Detalles Bibliográficos
Autores principales: Eisner, Teresa, Kostenko, Arseni, Hanusch, Franziska, Inoue, Shigeyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092829/
https://www.ncbi.nlm.nih.gov/pubmed/36098491
http://dx.doi.org/10.1002/chem.202202330

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092829/
https://www.ncbi.nlm.nih.gov/pubmed/36098491
http://dx.doi.org/10.1002/chem.202202330

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