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Fragile intermediate identification and reactivity elucidation in electrochemical oxidative α-C(sp(3))–H functionalization of tertiary amines
The direct α-C(sp(3))–H functionalization of widely available tertiary amines holds promise for the rapid construction of complex amine architectures. The activation of C(sp(3))–H bonds through electron transfer and proton transfer by oxidants, photoredox catalysis and electrochemical oxidation have...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10094091/ https://www.ncbi.nlm.nih.gov/pubmed/37063790 http://dx.doi.org/10.1039/d3sc00527e |