Fragile intermediate identification and reactivity elucidation in electrochemical oxidative α-C(sp(3))–H functionalization of tertiary amines

The direct α-C(sp(3))–H functionalization of widely available tertiary amines holds promise for the rapid construction of complex amine architectures. The activation of C(sp(3))–H bonds through electron transfer and proton transfer by oxidants, photoredox catalysis and electrochemical oxidation have...

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Detalles Bibliográficos
Autores principales: Liang, Kailun, Zhang, Dongmei, Su, Yanming, Lu, Lijun, Hu, Jun, Chen, Yi-Hung, Zhang, Xinxing, Lei, Aiwen, Yi, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10094091/
https://www.ncbi.nlm.nih.gov/pubmed/37063790
http://dx.doi.org/10.1039/d3sc00527e

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