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Fully-fused boron-doped olympicenes: modular synthesis, tunable optoelectronic properties, and one-electron reduction

We report here a novel family of boraolympicenes, structurally featuring boron-doping at the concave 11a-position of their π-skeletons and synthetically prepared via a facile one-pot triply borylation-based double-fold borocyclization reaction. Despite having no bulky protecting groups, these boraol...

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Detalles Bibliográficos
Autores principales: Guo, Jing, Zhang, Kaihua, Wang, Yanpei, Wei, Haipeng, Xiao, Wang, Yang, Kun, Zeng, Zebing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10094210/
https://www.ncbi.nlm.nih.gov/pubmed/37063807
http://dx.doi.org/10.1039/d3sc00342f