Palladium-Catalyzed Stereoselective Construction of 1,3-Stereocenters Displaying Axial and Central Chirality via Asymmetric Alkylations

The concurrent construction of 1,3-stereocenters remains a challenge. Herein, we report the development of stereoselective union of a point chiral center with allenyl axial chirality in 1,3-position by Pd-catalyzed asymmetric allenylic alkylation between racemic allenyl carbonates and indanone-deriv...

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Detalles Bibliográficos
Autores principales: Xue, Aiqi, Wei, Xingfu, Huang, Yue, Qu, Jingping, Wang, Baomin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10096308/
https://www.ncbi.nlm.nih.gov/pubmed/37049689
http://dx.doi.org/10.3390/molecules28072927

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10096308/
https://www.ncbi.nlm.nih.gov/pubmed/37049689
http://dx.doi.org/10.3390/molecules28072927

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