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Ligand field tuning of d-orbital energies in metal-organic framework clusters

Linker functionalization is a common route used to affect the electronic and catalytic properties of metal-organic frameworks. By either pre- or post-synthetically installing linkages with differing linker moieties the band gap, workfunction, and exciton lifetimes have been shown to be affected. One...

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Detalles Bibliográficos
Autores principales: Diamond, Brian G., Payne, Lillian I., Hendon, Christopher H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10097619/
https://www.ncbi.nlm.nih.gov/pubmed/37045986
http://dx.doi.org/10.1038/s42004-023-00863-z