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Chiral‐at‐Metal Silver‐Mediated Base Pairs: Metal‐Centred Chirality versus DNA Helical Chirality

When covalently incorporating ligands capable of forming chiral metal complexes into a DNA oligonucleotide duplex, an enantiospecific formation of metal‐mediated base pairs is possible. We have been investigating the chirality of the silver‐mediated base pair P−Ag(I)−P (P, 1H‐imidazo[4,5‐f][1,10]phe...

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Detalles Bibliográficos
Autores principales: Lefringhausen, Nils, Seiffert, Victoria, Erbacher, Catharina, Karst, Uwe, Müller, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10098492/
https://www.ncbi.nlm.nih.gov/pubmed/36219466
http://dx.doi.org/10.1002/chem.202202630