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Host Spin‐Crossover Thermodynamics Indicate Guest Fit

Spin‐crossover (SCO) metal‐organic cages capable of switching between high‐spin and low‐spin states have the potential to be used as magnetic sensors and switches. Variation of the donor strength of heterocyclic aldehyde subcomponents in imine‐based ligands can tune the ligand field for a Fe(II) cen...

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Detalles Bibliográficos
Autores principales: Zheng, Jieyu, von Krbek, Larissa K. S., Ronson, Tanya K., Nitschke, Jonathan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10098494/
https://www.ncbi.nlm.nih.gov/pubmed/36264645
http://dx.doi.org/10.1002/anie.202212634