Dioxygen Splitting by a Tantalum(V) Complex Ligated by a Rigid, Redox Non‐Innocent Pincer Ligand

The reaction of TaMe(3)Cl(2) with the rigid acridane‐derived trisamine H(3)NNN yields the tantalum(V) complex [TaCl(2)(NNN(cat))]. Subsequent reaction with dioxygen results in the full four‐electron reduction of O(2) yielding the oxido‐bridged bimetallic complex [{TaCl(2)(NNN(sq))}(2)O]. This dinucl...

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Detalles Bibliográficos
Autores principales: Underhill, Jack, Yang, Eric S., Schmidt‐Räntsch, Till, Myers, William K., Goicoechea, Jose M., Abbenseth, Josh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10098518/
https://www.ncbi.nlm.nih.gov/pubmed/36281622
http://dx.doi.org/10.1002/chem.202203266

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10098518/
https://www.ncbi.nlm.nih.gov/pubmed/36281622
http://dx.doi.org/10.1002/chem.202203266

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