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Dioxygen Splitting by a Tantalum(V) Complex Ligated by a Rigid, Redox Non‐Innocent Pincer Ligand
The reaction of TaMe(3)Cl(2) with the rigid acridane‐derived trisamine H(3)NNN yields the tantalum(V) complex [TaCl(2)(NNN(cat))]. Subsequent reaction with dioxygen results in the full four‐electron reduction of O(2) yielding the oxido‐bridged bimetallic complex [{TaCl(2)(NNN(sq))}(2)O]. This dinucl...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10098518/ https://www.ncbi.nlm.nih.gov/pubmed/36281622 http://dx.doi.org/10.1002/chem.202203266 |