Reactivity of Sodium Pentaphospholide Na[cyclo‐P(5)] towards C≡E (E=C, N, P) Triple Bonds

A diglyme solution of Na[cyclo‐P(5)] (1) reacts with alkynes and isolobal nitriles and phosphaalkynes to afford the otherwise elusive (aza)phospholide anions 2  a–c, 4  a,b, and 6. The reaction of Na[cyclo‐P(5)] with alkynes and nitriles was studied by means of DFT methods, which suggested a concert...

Descripción completa

Detalles Bibliográficos
Autores principales: Petrov, Andrey, Conrad, Lawrence, Coles, Nathan T., Weber, Manuela, Andrae, Dirk, Zagidullin, Almaz, Miluykov, Vasili, Müller, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10098531/
https://www.ncbi.nlm.nih.gov/pubmed/36210344
http://dx.doi.org/10.1002/chem.202203056

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10098531/
https://www.ncbi.nlm.nih.gov/pubmed/36210344
http://dx.doi.org/10.1002/chem.202203056

Ejemplares similares