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Reactivity of Sodium Pentaphospholide Na[cyclo‐P(5)] towards C≡E (E=C, N, P) Triple Bonds

A diglyme solution of Na[cyclo‐P(5)] (1) reacts with alkynes and isolobal nitriles and phosphaalkynes to afford the otherwise elusive (aza)phospholide anions 2 a–c, 4 a,b, and 6. The reaction of Na[cyclo‐P(5)] with alkynes and nitriles was studied by means of DFT methods, which suggested a concert...

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Detalles Bibliográficos
Autores principales:	Petrov, Andrey, Conrad, Lawrence, Coles, Nathan T., Weber, Manuela, Andrae, Dirk, Zagidullin, Almaz, Miluykov, Vasili, Müller, Christian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10098531/ https://www.ncbi.nlm.nih.gov/pubmed/36210344 http://dx.doi.org/10.1002/chem.202203056

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