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Stacking Interactions: A Supramolecular Approach to Upgrade Weak Halogen Bond Donors

The co‐crystallization of tetracyanobenzene (TCB) with haloarenes ArX provided six new co‐crystals TCB ⋅ ArX (ArX=PhCl, PhBr, 4‐MeC(6)H(4)Cl, 4‐MeC(6)H(4)Br, 4‐MeOC(6)H(4)Cl, 1,2‐Br(2)C(6)H(4)) which were studied by X‐ray diffraction. In these systems, the strong collective effect of π⋅⋅⋅π stacking...

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Detalles Bibliográficos
Autores principales: Baykov, Sergey V., Ivanov, Daniil M., Kasatkina, Svetlana O., Galmés, Bartomeu, Frontera, Antonio, Resnati, Giuseppe, Kukushkin, Vadim Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099561/
https://www.ncbi.nlm.nih.gov/pubmed/36178324
http://dx.doi.org/10.1002/chem.202201869