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A Potent Auto‐Umpolung Ligand for Conjugative Radical Stabilization

Carbenes with conjugatively connected redox system act as “auto‐umpolung” ligands. Due to their electronic flexibility, they should also be particularly suitable to stabilize open‐shell species. Herein, the first neutral radical of such sort is described in form of a dialkylamino‐substituted bis(dic...

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Detalles Bibliográficos
Autores principales: Holthoff, Jana M., Engelage, Elric, Ruff, Adrian, Galazzo, Laura, Bordignon, Enrica, Huber, Stefan M., Weiss, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099569/
https://www.ncbi.nlm.nih.gov/pubmed/36239437
http://dx.doi.org/10.1002/chem.202203149