Room‐Temperature Solid‐State Transformation of Na(4)SnS(4) ⋅ 14H(2)O into Na(4)Sn(2)S(6) ⋅ 5H(2)O: An Unusual Epitaxial Reaction Including Bond Formation, Mass Transport, and Ionic Conductivity

A highly unusual solid‐state epitaxy‐induced phase transformation of Na(4)SnS(4) ⋅ 14H(2)O (I) into Na(4)Sn(2)S(6) ⋅ 5H(2)O (II) occurs at room temperature. Ab initio molecular dynamics (AIMD) simulations indicate an internal acid‐base reaction to form [SnS(3)SH](3−) which condensates to [Sn(2)S(6)]...

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Detalles Bibliográficos
Autores principales: Benkada, Assma, Hartmann, Felix, A. Engesser, Tobias, Indris, Sylvio, Zinkevich, Tatiana, Näther, Christian, Lühmann, Henning, Reinsch, Helge, Adams, Stefan, Bensch, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099607/
https://www.ncbi.nlm.nih.gov/pubmed/36214658
http://dx.doi.org/10.1002/chem.202202318

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099607/
https://www.ncbi.nlm.nih.gov/pubmed/36214658
http://dx.doi.org/10.1002/chem.202202318

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