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The HD Reaction of Nitrogenase: a Detailed Mechanism
Nitrogenase is the enzyme that converts N(2) to NH(3) under ambient conditions. The chemical mechanism of this catalysis at the active site FeMo‐co [Fe(7)S(9)CMo(homocitrate)] is unknown. An obligatory co‐product is H(2), while exogenous H(2) is a competitive inhibitor. Isotopic substitution using e...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099629/ https://www.ncbi.nlm.nih.gov/pubmed/36274057 http://dx.doi.org/10.1002/chem.202202502 |