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Conversion of a Au(I) Fluorido Complex into an N‐Fluoroamido Derivative: N−F versus Au−N Reactivity
The Au(I) complex [Au{N(F)SO(2)Ph}(SPhos)] (SPhos=dicyclohexyl(2′,6′‐dimethoxy[1,1′‐biphenyl]‐2‐yl)phosphane) (2) bearing a fluoroamido ligand has been synthesized by reaction of the fluorido complex [Au(F)(SPhos)] (1) with NFSI (NFSI=N‐fluorobenzenesulfonimide). A reaction with CO resulted in an un...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099710/ https://www.ncbi.nlm.nih.gov/pubmed/36279190 http://dx.doi.org/10.1002/anie.202212858 |