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Conversion of a Au(I) Fluorido Complex into an N‐Fluoroamido Derivative: N−F versus Au−N Reactivity

The Au(I) complex [Au{N(F)SO(2)Ph}(SPhos)] (SPhos=dicyclohexyl(2′,6′‐dimethoxy[1,1′‐biphenyl]‐2‐yl)phosphane) (2) bearing a fluoroamido ligand has been synthesized by reaction of the fluorido complex [Au(F)(SPhos)] (1) with NFSI (NFSI=N‐fluorobenzenesulfonimide). A reaction with CO resulted in an un...

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Detalles Bibliográficos
Autores principales:	Rachor, Simon G., Ahrens, Mike, Braun, Thomas
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099710/ https://www.ncbi.nlm.nih.gov/pubmed/36279190 http://dx.doi.org/10.1002/anie.202212858

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