Actinide Pnictinidene Chemistry: A Terminal Thorium Parent‐Arsinidene Complex Stabilised by a Super‐Bulky Triamidoamine Ligand

We report the direct synthesis of the terminal pnictidenes [An(Tren(TCHS))(PnH)][M(2,2,2‐cryptand)] (Tren(TCHS)={N(CH(2)CH(2)NSiCy(3))(3)}(3−); An/Pn/M=Th/P/Na 5, Th/As/K 6, U/P/Na 7, U/As/K 8) and their conversion to the pnictides [An(Tren(TCHS))(PnH(2))] (An/Pn=Th/P 9, Th/As 10, U/P 11, U/As 12)....

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Detalles Bibliográficos
Autores principales: Du, Jingzhen, Balázs, Gábor, Seed, John A., Cryer, Jonathan D., Wooles, Ashley J., Scheer, Manfred, Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099757/
https://www.ncbi.nlm.nih.gov/pubmed/36254899
http://dx.doi.org/10.1002/anie.202211627

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099757/
https://www.ncbi.nlm.nih.gov/pubmed/36254899
http://dx.doi.org/10.1002/anie.202211627

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