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Iron‐Catalyzed Borylation of Propargylic Acetates for the Synthesis of Multisubstituted Allenylboronates

A novel iron‐catalyzed borylation of propargylic acetates leading to allenylboronates has been developed. The method allows the preparation of a variety of di‐, tri‐ and tetrasubstituted allenylboronates at room temperature with good functional group compatibility. Stereochemical studies show that a...

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Detalles Bibliográficos
Autores principales: Bermejo‐López, Aitor, Kong, Wei‐Jun, Tortajada, Pedro J., Posevins, Daniels, Martín‐Matute, Belén, Bäckvall, Jan‐E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099795/
https://www.ncbi.nlm.nih.gov/pubmed/36250587
http://dx.doi.org/10.1002/chem.202203130