Photo‐Induced Homologation of Carbonyl Compounds for Iterative Syntheses

We describe a photo‐induced reaction for the in situ generation of highly reactive alkyl diazo species from carbonyl precursors via photo‐excitation of N‐tosylhydrazone anions. The diazo intermediates undergo efficient C−H insertion of aldehydes, leading to the productive synthesis of aldehydes and...

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Detalles Bibliográficos
Autores principales: Wang, Hua, Wang, Shun, George, Vincent, Llorente, Galder, König, Burkhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099875/
https://www.ncbi.nlm.nih.gov/pubmed/36226924
http://dx.doi.org/10.1002/anie.202211578

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099875/
https://www.ncbi.nlm.nih.gov/pubmed/36226924
http://dx.doi.org/10.1002/anie.202211578

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