Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond

In this contribution, we illustrate uranium complexes bearing a pendant borate (i.e. 1 and 2) or a pendant borane (i.e. 3 and 4) moiety via reaction of the highly strained uranacycle I with various 3‐coordinate boranes. Complexes 3 and 4 represent the first examples of uranium complexes with a penda...

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Detalles Bibliográficos
Autores principales: Su, Wei, Rajeshkumar, Thayalan, Xiang, Libo, Maron, Laurent, Ye, Qing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099876/
https://www.ncbi.nlm.nih.gov/pubmed/36256540
http://dx.doi.org/10.1002/anie.202212823

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099876/
https://www.ncbi.nlm.nih.gov/pubmed/36256540
http://dx.doi.org/10.1002/anie.202212823

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