Umpolung Synthesis of Pyridyl Ethers by Bi(V)‐Mediated O‐Arylation of Pyridones

We report that O‐selective arylation of 2‐ and 4‐pyridones with arylboronic acids is affected by a modular, bismacycle‐based system. The utility of this umpolung approach to pyridyl ethers, which is complementary to conventional methods based on S(N)Ar or cross‐coupling, is demonstrated through the...

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Detalles Bibliográficos
Autores principales: Ruffell, Katie, Gallegos, Liliana C., Ling, Kenneth B., Paton, Robert S., Ball, Liam T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099949/
https://www.ncbi.nlm.nih.gov/pubmed/36251336
http://dx.doi.org/10.1002/anie.202212873

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099949/
https://www.ncbi.nlm.nih.gov/pubmed/36251336
http://dx.doi.org/10.1002/anie.202212873

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