Catalytic Reversible (De)hydrogenation To Rotate a Chemically Fueled Molecular Switch

We report here the development of a rotating molecular switch based on metal‐catalyzed reversible (de)‐hydrogenation. Under an argon atmosphere, acceptorless dehydrogenation induces a switch from an alcohol to a ketone, while reversing to a hydrogen pressure switches back the system to the alcohol....

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Detalles Bibliográficos
Autores principales: Olivieri, Enzo, Shao, Na, Rosas, Roselyne, Naubron, Jean‐Valère, Quintard, Adrien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099969/
https://www.ncbi.nlm.nih.gov/pubmed/36226997
http://dx.doi.org/10.1002/anie.202214763

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099969/
https://www.ncbi.nlm.nih.gov/pubmed/36226997
http://dx.doi.org/10.1002/anie.202214763

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