Carbodicarbenes and Striking Redox Transitions of their Conjugate Acids: Influence of NHC versus CAAC as Donor Substituents

Herein, a new type of carbodicarbene (CDC) comprising two different classes of carbenes is reported; NHC and CAAC as donor substituents and compare the molecular structure and coordination to Au(I)Cl to those of NHC‐only and CAAC‐only analogues. The conjugate acids of these three CDCs exhibit notabl...

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Detalles Bibliográficos
Autores principales: Dolai, Ramapada, Kumar, Rahul, Elvers, Benedict J., Pal, Pradeep Kumar, Joseph, Benson, Sikari, Rina, Nayak, Mithilesh Kumar, Maiti, Avijit, Singh, Tejender, Chrysochos, Nicolas, Jayaraman, Arumugam, Krummenacher, Ivo, Mondal, Jagannath, Priyakumar, U. Deva, Braunschweig, Holger, Yildiz, Cem B., Schulzke, Carola, Jana, Anukul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100033/
https://www.ncbi.nlm.nih.gov/pubmed/36129127
http://dx.doi.org/10.1002/chem.202202888

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100033/
https://www.ncbi.nlm.nih.gov/pubmed/36129127
http://dx.doi.org/10.1002/chem.202202888

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