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Carbodicarbenes and Striking Redox Transitions of their Conjugate Acids: Influence of NHC versus CAAC as Donor Substituents
Herein, a new type of carbodicarbene (CDC) comprising two different classes of carbenes is reported; NHC and CAAC as donor substituents and compare the molecular structure and coordination to Au(I)Cl to those of NHC‐only and CAAC‐only analogues. The conjugate acids of these three CDCs exhibit notabl...
Autores principales: | Dolai, Ramapada, Kumar, Rahul, Elvers, Benedict J., Pal, Pradeep Kumar, Joseph, Benson, Sikari, Rina, Nayak, Mithilesh Kumar, Maiti, Avijit, Singh, Tejender, Chrysochos, Nicolas, Jayaraman, Arumugam, Krummenacher, Ivo, Mondal, Jagannath, Priyakumar, U. Deva, Braunschweig, Holger, Yildiz, Cem B., Schulzke, Carola, Jana, Anukul |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100033/ https://www.ncbi.nlm.nih.gov/pubmed/36129127 http://dx.doi.org/10.1002/chem.202202888 |
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