Zirconium Carbide Mediates Coke‐Resistant Methane Dry Reforming on Nickel‐Zirconium Catalysts

Graphitic deposits anti‐segregate into Ni(0) nanoparticles to provide restored CH(4) adsorption sites and near‐surface/dissolved C atoms, which migrate to the Ni(0)/ZrO(2) interface and induce local Zr( x )C( y ) formation. The resulting oxygen‐deficient carbidic phase boundary sites assist in the k...

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Detalles Bibliográficos
Autores principales: Haug, Leander, Thurner, Christoph, Bekheet, Maged F., Bischoff, Benjamin, Gurlo, Aleksander, Kunz, Martin, Sartory, Bernhard, Penner, Simon, Klötzer, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100075/
https://www.ncbi.nlm.nih.gov/pubmed/36379010
http://dx.doi.org/10.1002/anie.202213249

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100075/
https://www.ncbi.nlm.nih.gov/pubmed/36379010
http://dx.doi.org/10.1002/anie.202213249

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