A Hydride‐Substituted Homoleptic Silylborate: How Similar is it to its Diborane(6)‐Dianion Isostere?

The B‐nucleophilic 9H‐9‐borafluorene dianion reacts with 9‐chloro‐9‐silafluorene to afford air‐ and moisture‐stable silylborate salts M[Ar(2)(H)B−Si(H)Ar(2)] (M[HBSiH], M=Li, Na). Li[HBSiH] and Me(3)SiCl give the B−pyridine adduct Ar(2)(py)B−Si(H)Ar(2) ((py)BSiH) or the chlorosilane Li[Ar(2)(H)B−Si(...

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Detalles Bibliográficos
Autores principales: Gilmer, Jannik, Bolte, Michael, Virovets, Alexander, Lerner, Hans‐Wolfram, Fantuzzi, Felipe, Wagner, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100083/
https://www.ncbi.nlm.nih.gov/pubmed/36210643
http://dx.doi.org/10.1002/chem.202203119

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100083/
https://www.ncbi.nlm.nih.gov/pubmed/36210643
http://dx.doi.org/10.1002/chem.202203119

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