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A Hydride‐Substituted Homoleptic Silylborate: How Similar is it to its Diborane(6)‐Dianion Isostere?
The B‐nucleophilic 9H‐9‐borafluorene dianion reacts with 9‐chloro‐9‐silafluorene to afford air‐ and moisture‐stable silylborate salts M[Ar(2)(H)B−Si(H)Ar(2)] (M[HBSiH], M=Li, Na). Li[HBSiH] and Me(3)SiCl give the B−pyridine adduct Ar(2)(py)B−Si(H)Ar(2) ((py)BSiH) or the chlorosilane Li[Ar(2)(H)B−Si(...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100083/ https://www.ncbi.nlm.nih.gov/pubmed/36210643 http://dx.doi.org/10.1002/chem.202203119 |