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Anionic Magnesium and Calcium Hydrides: Transforming CO into Unsaturated Disilyl Ethers

The synthesis, characterisation and reactivity of two isostructural anionic magnesium and calcium complexes is reported. By X‐ray and neutron diffraction techniques, the anionic hydrides are shown to exist as dimers, held together by a range of interactions between the two anions and two bridging po...

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Detalles Bibliográficos
Autores principales: McMullen, Jacob S., Huo, Ryan, Vasko, Petra, Edwards, Alison J., Hicks, Jamie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100151/
https://www.ncbi.nlm.nih.gov/pubmed/36344462
http://dx.doi.org/10.1002/anie.202215218