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Atroposelective Synthesis of 2,2′‐Bis(arylamino)‐1,1′‐biaryls by Oxidative Iron(III)‐ and Phosphoric Acid‐Catalyzed C−C Coupling of Diarylamines
We describe an iron‐catalyzed asymmetric oxidative C−C coupling of diarylamines which proceeds at room temperature with air as final oxidant. Using hexadecafluorophthalocyanine‐iron(II) as catalyst in the presence of catalytic amounts of an axially chiral biaryl phosphoric acid, the resulting chiral...
Huvudupphovsmän: | , , , |
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Materialtyp: | Online Artikel Text |
Språk: | English |
Publicerad: |
John Wiley and Sons Inc.
2022
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Ämnen: | |
Länkar: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100243/ https://www.ncbi.nlm.nih.gov/pubmed/36269611 http://dx.doi.org/10.1002/chem.202203269 |