Atroposelective Synthesis of 2,2′‐Bis(arylamino)‐1,1′‐biaryls by Oxidative Iron(III)‐ and Phosphoric Acid‐Catalyzed C−C Coupling of Diarylamines

We describe an iron‐catalyzed asymmetric oxidative C−C coupling of diarylamines which proceeds at room temperature with air as final oxidant. Using hexadecafluorophthalocyanine‐iron(II) as catalyst in the presence of catalytic amounts of an axially chiral biaryl phosphoric acid, the resulting chiral...

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Detalles Bibliográficos
Autores principales: Fritsche, Raphael F., Schuh, Tristan, Kataeva, Olga, Knölker, Hans‐Joachim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100243/
https://www.ncbi.nlm.nih.gov/pubmed/36269611
http://dx.doi.org/10.1002/chem.202203269

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100243/
https://www.ncbi.nlm.nih.gov/pubmed/36269611
http://dx.doi.org/10.1002/chem.202203269

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