A Silicon‐Stereogenic Silanol ‐ (18)O‐Isotope Labeling and Stereogenic Probe Reveals Hidden Stereospecific Water Exchange Reaction

A silicon‐stereogenic aminosilanol was isolated in excellent diastereomeric ratio and the absolute configuration was determined. The silanol is configurative and condensation stable in solution and shows stereoselective transformations with a clean stereospecific pathway in follow‐up reactions, whic...

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Detalles Bibliográficos
Autores principales: Langenohl, Felix, Rösler, Jonas, Zühlke, Sebastian, Kirchhoff, Jan‐Lukas, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100314/
https://www.ncbi.nlm.nih.gov/pubmed/36166278
http://dx.doi.org/10.1002/chem.202202935

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100314/
https://www.ncbi.nlm.nih.gov/pubmed/36166278
http://dx.doi.org/10.1002/chem.202202935

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