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Activation of Ge−H and Sn−H Bonds with N‐Heterocyclic Carbenes and a Cyclic (Alkyl)(amino)carbene

A study of the reactivity of several N‐heterocyclic carbenes (NHCs) and the cyclic (alkyl)(amino)carbene 1‐(2,6‐di‐iso‐propylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene (cAAC(Me)) with the group 14 hydrides GeH(2)Mes(2) and SnH(2)Me(2) (Me=CH(3), Mes=1,3,5‐(CH(3))(3)C(6)H(2)) is presented. The...

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Detalles Bibliográficos
Autores principales: Philipp, Michael S. M., Bertermann, Rüdiger, Radius, Udo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100474/
https://www.ncbi.nlm.nih.gov/pubmed/36177710
http://dx.doi.org/10.1002/chem.202202493