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Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions

The synthesis and characterization of a series of Mo(iv) bis-β-diketonate ((R)diket, R = Me, (t)Bu, Ph) dichloride ((R)Mo(IV)Cl(2)) and bistriflate ((R)Mo(IV)(OTf)(2)) complexes are reported. All complexes are characterized in solid and solution state by XRD and (1)H NMR spectroscopy. We demonstrate...

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Detalles Bibliográficos
Autores principales: Masero, Fabio, Mougel, Victor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10101048/
https://www.ncbi.nlm.nih.gov/pubmed/36987978
http://dx.doi.org/10.1039/d3cc00572k