Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions

The synthesis and characterization of a series of Mo(iv) bis-β-diketonate ((R)diket, R = Me, (t)Bu, Ph) dichloride ((R)Mo(IV)Cl(2)) and bistriflate ((R)Mo(IV)(OTf)(2)) complexes are reported. All complexes are characterized in solid and solution state by XRD and (1)H NMR spectroscopy. We demonstrate...

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Detalles Bibliográficos
Autores principales: Masero, Fabio, Mougel, Victor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10101048/
https://www.ncbi.nlm.nih.gov/pubmed/36987978
http://dx.doi.org/10.1039/d3cc00572k
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author Masero, Fabio
Mougel, Victor
author_facet Masero, Fabio
Mougel, Victor
author_sort Masero, Fabio
collection PubMed
description The synthesis and characterization of a series of Mo(iv) bis-β-diketonate ((R)diket, R = Me, (t)Bu, Ph) dichloride ((R)Mo(IV)Cl(2)) and bistriflate ((R)Mo(IV)(OTf)(2)) complexes are reported. All complexes are characterized in solid and solution state by XRD and (1)H NMR spectroscopy. We demonstrate that the bistriflate complexes constitute highly active catalysts for allylic substitution reactions.
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spelling pubmed-101010482023-04-14 Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions Masero, Fabio Mougel, Victor Chem Commun (Camb) Chemistry The synthesis and characterization of a series of Mo(iv) bis-β-diketonate ((R)diket, R = Me, (t)Bu, Ph) dichloride ((R)Mo(IV)Cl(2)) and bistriflate ((R)Mo(IV)(OTf)(2)) complexes are reported. All complexes are characterized in solid and solution state by XRD and (1)H NMR spectroscopy. We demonstrate that the bistriflate complexes constitute highly active catalysts for allylic substitution reactions. The Royal Society of Chemistry 2023-03-14 /pmc/articles/PMC10101048/ /pubmed/36987978 http://dx.doi.org/10.1039/d3cc00572k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Masero, Fabio
Mougel, Victor
Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions
title Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions
title_full Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions
title_fullStr Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions
title_full_unstemmed Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions
title_short Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions
title_sort molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10101048/
https://www.ncbi.nlm.nih.gov/pubmed/36987978
http://dx.doi.org/10.1039/d3cc00572k
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AT mougelvictor molybdenumivbdiketonatecomplexesashighlyactivecatalystsforallylicsubstitutionreactions

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