Cargando…
Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions
The synthesis and characterization of a series of Mo(iv) bis-β-diketonate ((R)diket, R = Me, (t)Bu, Ph) dichloride ((R)Mo(IV)Cl(2)) and bistriflate ((R)Mo(IV)(OTf)(2)) complexes are reported. All complexes are characterized in solid and solution state by XRD and (1)H NMR spectroscopy. We demonstrate...
Autores principales: | Masero, Fabio, Mougel, Victor |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10101048/ https://www.ncbi.nlm.nih.gov/pubmed/36987978 http://dx.doi.org/10.1039/d3cc00572k |
Ejemplares similares
-
Regioselective molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications
por: Salman, Muhammad, et al.
Publicado: (2020) -
Direct and Highly Regioselective and Enantioselective Allylation of β-Diketones
por: Chalifoux, Wesley A., et al.
Publicado: (2012) -
A bioinspired molybdenum–copper molecular catalyst for CO(2) electroreduction
por: Mouchfiq, Ahmed, et al.
Publicado: (2020) -
An investigation of the allylation cascade reactions of substituted indigos
por: Perry, Matthew J., et al.
Publicado: (2023) -
Boron-catalyzed dehydrative allylation of 1,3-diketones and β-ketone esters with 1,3-diarylallyl alcohols in water
por: Zhang, Guo-Min, et al.
Publicado: (2021)