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Polarizable Anionic Sublattices Can Screen Molecular Dipoles in Noncentrosymmetric Inorganic–Organic Hybrids

[Image: see text] We report the growth and photophysical characterization of two polar hybrid lead halide phases, methylenedianiline lead iodide and bromide, (MDA)Pb(2)I(6) and (MDA)Pb(2)Br(6), respectively. The phases crystallize in noncentrosymmetric space group Fdd2, which produces a highly orien...

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Detalles Bibliográficos
Autores principales: Cassingham, Megan A., Goh, Yang G., McClure, Eric T., Hodgkins, Taylor L., Zhang, Weiguo, Liang, Mingli, Dawlaty, Jahan M., Djurovich, Peter I., Haiges, Ralf, Halasyamani, P. Shiv, Savory, Christopher N., Thompson, Mark E., Melot, Brent C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10103049/
https://www.ncbi.nlm.nih.gov/pubmed/36987567
http://dx.doi.org/10.1021/acsami.2c20648