A {Gd(12)Na(6)} Molecular Quadruple-Wheel with a Record Magnetocaloric Effect at Low Magnetic Fields and Temperatures

[Image: see text] Reaction of Gd(OAc)(3)·4H(2)O, salicylaldehyde and CH(3)ONa in MeCN/MeOH affords [Gd(12)Na(6)(OAc)(25)(HCO(2))(5)(CO(3))(6)(H(2)O)(12)]·9H(2)O.0.5MeCN (1·9H(2)O.0.5MeCN), whose structure describes a quadruple-wheel consisting of two {Na(3)} and two {Gd(6)} rings. The magnetic prope...

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Detalles Bibliográficos
Autores principales: Tziotzi, Thomais G., Gracia, David, Dalgarno, Scott J., Schnack, Jürgen, Evangelisti, Marco, Brechin, Euan K., Milios, Constantinos J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10103126/
https://www.ncbi.nlm.nih.gov/pubmed/37010322
http://dx.doi.org/10.1021/jacs.3c01610

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10103126/
https://www.ncbi.nlm.nih.gov/pubmed/37010322
http://dx.doi.org/10.1021/jacs.3c01610

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