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A {Gd(12)Na(6)} Molecular Quadruple-Wheel with a Record Magnetocaloric Effect at Low Magnetic Fields and Temperatures
[Image: see text] Reaction of Gd(OAc)(3)·4H(2)O, salicylaldehyde and CH(3)ONa in MeCN/MeOH affords [Gd(12)Na(6)(OAc)(25)(HCO(2))(5)(CO(3))(6)(H(2)O)(12)]·9H(2)O.0.5MeCN (1·9H(2)O.0.5MeCN), whose structure describes a quadruple-wheel consisting of two {Na(3)} and two {Gd(6)} rings. The magnetic prope...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10103126/ https://www.ncbi.nlm.nih.gov/pubmed/37010322 http://dx.doi.org/10.1021/jacs.3c01610 |