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Olefination of carbonyls with alkenes enabled by electrophotocatalytic generation of distonic radical cations

The conversion of carbonyls to olefins is a transformation of great importance for complex molecule synthesis. Standard methods use stoichiometric reagents that have poor atom economy and require strongly basic conditions, which limit their functional group compatibility. An ideal solution would be...

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Detalles Bibliográficos
Autores principales: Steiniger, Keri A., Lambert, Tristan H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10104462/
https://www.ncbi.nlm.nih.gov/pubmed/37058559
http://dx.doi.org/10.1126/sciadv.adg3026