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Boosting Ring Strain and Lewis Acidity of Borirane: Synthesis, Reactivity and Density Functional Theory Studies of an Uncoordinated Arylborirane Fused to o‐Carborane

Among the parent borirane, benzoborirene and ortho‐dicarbadodecaborane‐fused borirane, the latter possesses the highest ring strain and the highest Lewis acidity according to our density functional theory (DFT) studies. The synthesis of this class of compounds is thus considerably challenging. The e...

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Detalles Bibliográficos
Autores principales: Wei, Yuxiang, Wang, Junyi, Yang, Weiguang, Lin, Zhenyang, Ye, Qing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107145/
https://www.ncbi.nlm.nih.gov/pubmed/36278311
http://dx.doi.org/10.1002/chem.202203265