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Stable Luminescent [Cu(NN)(PP)](+) Complexes Incorporating a β‐Cyclodextrin‐Based Diphosphane Ligand with Metal‐Confining Properties

A β‐cyclodextrin‐based diphosphane with metal‐confining properties was efficiently synthesized thanks to an unprecedented Smiles‐like rearrangement of diphenyl‐(2‐phosphanylphenyl)phosphane in the presence of excess n‐BuLi. The cis‐chelating bidentate ligand is capable of forming very stable heterol...

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Detalles Bibliográficos
Autores principales: Phan, Tuan‐Anh, Armaroli, Nicola, Saavedra Moncada, Alejandra, Bandini, Elisa, Delavaux‐Nicot, Béatrice, Nierengarten, Jean‐François, Armspach, Dominique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107221/
https://www.ncbi.nlm.nih.gov/pubmed/36433744
http://dx.doi.org/10.1002/anie.202214638