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Phospholenes from Phosphabenzenes by Selective Ring Contraction

A 3‐amino‐functionalized phosphabenzene (phosphinine) has been synthesized and structurally characterized. The pyramidalized nitrogen atom of the dimethylamino substituent indicates only a weak interaction between the lone pair of the nitrogen atom and the aromatic phosphorus heterocycle, resulting...

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Detalles Bibliográficos
Autores principales: Lin, Jinxiong, Coles, Nathan T., Dettling, Lea, Steiner, Luca, Felix Witte, J., Paulus, Beate, Müller, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107248/
https://www.ncbi.nlm.nih.gov/pubmed/36383093
http://dx.doi.org/10.1002/chem.202203406