Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity

Two oxoiron(IV) isomers (( R ) 2a and ( R ) 2b) of general formula [Fe(IV)(O)((R)PyNMe(3))(CH(3)CN)](2+) are obtained by reaction of their iron(II) precursor with NBu(4)IO(4). The two isomers differ in the position of the oxo ligand, cis and trans to the pyridine donor. The mechanism of isomerizatio...

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Detalles Bibliográficos
Autores principales: Dantignana, Valeria, Pérez‐Segura, M. Carmen, Besalú‐Sala, Pau, Delgado‐Pinar, Estefanía, Martínez‐Camarena, Álvaro, Serrano‐Plana, Joan, Álvarez‐Núñez, Andrea, Castillo, Carmen E., García‐España, Enrique, Luis, Josep M., Basallote, Manuel G., Costas, Miquel, Company, Anna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107328/
https://www.ncbi.nlm.nih.gov/pubmed/36305539
http://dx.doi.org/10.1002/anie.202211361

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107328/
https://www.ncbi.nlm.nih.gov/pubmed/36305539
http://dx.doi.org/10.1002/anie.202211361

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