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Cyanide Binding to [FeFe]‐Hydrogenase Stabilizes the Alternative Configuration of the Proton Transfer Pathway
Hydrogenases are H(2) converting enzymes that harbor catalytic cofactors in which iron (Fe) ions are coordinated by biologically unusual carbon monoxide (CO) and cyanide (CN(−)) ligands. Extrinsic CO and CN(−), however, inhibit hydrogenases. The mechanism by which CN(−) binds to [FeFe]‐hydrogenases...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107461/ https://www.ncbi.nlm.nih.gov/pubmed/36464641 http://dx.doi.org/10.1002/anie.202216903 |