Electronic Control of the Scholl Reaction: Selective Synthesis of Spiro vs Helical Nanographenes

Scholl oxidation has become an essential reaction in the bottom‐up synthesis of molecular nanographenes. Herein, we describe a Scholl reaction controlled by the electronic effects on the starting substrate (1 a, b). Anthracene‐based polyphenylenes lead to spironanographenes under Scholl conditions....

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Detalles Bibliográficos
Autores principales: Izquierdo‐García, Patricia, Fernández‐García, Jesús M., Perles, Josefina, Fernández, Israel, Martín, Nazario
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107473/
https://www.ncbi.nlm.nih.gov/pubmed/36495528
http://dx.doi.org/10.1002/anie.202215655

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107473/
https://www.ncbi.nlm.nih.gov/pubmed/36495528
http://dx.doi.org/10.1002/anie.202215655

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