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Electronic Control of the Scholl Reaction: Selective Synthesis of Spiro vs Helical Nanographenes
Scholl oxidation has become an essential reaction in the bottom‐up synthesis of molecular nanographenes. Herein, we describe a Scholl reaction controlled by the electronic effects on the starting substrate (1 a, b). Anthracene‐based polyphenylenes lead to spironanographenes under Scholl conditions....
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107473/ https://www.ncbi.nlm.nih.gov/pubmed/36495528 http://dx.doi.org/10.1002/anie.202215655 |