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Pushing Photochemistry into Water: Acceleration of the Di‐π‐Methane Rearrangement and the Paternó‐Büchi Reaction “On‐Water”

Two representative organic photoreactions, namely a bimolecular photocycloaddition and a monomolecular photorearrangement, are presented that are accelerated when the reaction is performed “on‐water”, that is, at the water‐substrate interface with no solvation of the reaction components. According t...

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Detalles Bibliográficos
Autores principales: Schulte, Robin, Löcker, Marco, Ihmels, Heiko, Heide, Maximilian, Engelhard, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107481/
https://www.ncbi.nlm.nih.gov/pubmed/36398899
http://dx.doi.org/10.1002/chem.202203203