Bis(amidophenolato)phosphonium: Si−H Hydride Abstraction and Phosphorus‐Ligand Cooperative Activation of C−C Multiple Bonds

The first bis(amidophenolato)phosphonium salts are prepared and fully characterized. The perfluorinated derivative represents the strongest monocationic phosphorus Lewis acid on the fluoride and hydride ion affinity scale isolable to date. This affinity enables new reactions, such as hydride abstrac...

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Detalles Bibliográficos
Autores principales: Roth, Daniel, Thorwart, Thaddäus, Douglas, Clara, Greb, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107512/
https://www.ncbi.nlm.nih.gov/pubmed/36367087
http://dx.doi.org/10.1002/chem.202203024

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107512/
https://www.ncbi.nlm.nih.gov/pubmed/36367087
http://dx.doi.org/10.1002/chem.202203024

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